Influence of hydrogen on the morphology of platinum and palladium nanocrystals

Palladium and platinum nanocrystals are synthesized by the liquid-liquid phase transfer method, which is a suitable way to produce anisotropic metallic nanoparticles and control their shape at the nanoscopic scale. The process leading to shape control is, however, quite complex as all the physical a...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 10 vom: 13. März, Seite 4835-41
1. Verfasser: Salzemann, Caroline (VerfasserIn)
Weitere Verfasser: Petit, Christophe
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Palladium and platinum nanocrystals are synthesized by the liquid-liquid phase transfer method, which is a suitable way to produce anisotropic metallic nanoparticles and control their shape at the nanoscopic scale. The process leading to shape control is, however, quite complex as all the physical and chemical parameters could play an important role. In this paper, we have demonstrated the primordial role of the dissolved gases (O(2), H(2), N(2)) in the solvent medium on the nanomorphology of platinum and palladium nanocrystals. In particular, it shows the specific role of H(2) in the formation of platinum nanocubes 
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