Vertically oriented TiO(x)N(y) nanopillar arrays with embedded Ag nanoparticles for visible-light photocatalysis

© 2012 American Chemical Society

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 12 vom: 27. März, Seite 5427-31
1. Verfasser: Jiang, Weitao (VerfasserIn)
Weitere Verfasser: Ullah, Najeeb, Divitini, Giorgio, Ducati, Caterina, Kumar, R Vasant, Ding, Yucheng, Barber, Zoe H
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a We present a straightforward method to produce highly crystalline, vertically oriented TiO(x)N(y) nanopillars (up to 1 μm in length) with a band gap in the visible-light region. This process starts with reactive dc sputtering to produce a TiN porous film, followed by a simple oxidation process at elevated temperatures in oxygen or air. By controlling the oxidation conditions, the band gap of the prepared TiO(x)N(y) can be tuned to different wavelength within the range of visible light. Furthermore, in order to inhibit carrier recombination to enhance the photocatalytic activity, Ag nanoparticles have been embedded into the nanogaps between the TiO(x)N(y) pillars by photoinduced reduction of Ag(+) (aq) irradiated with visible light. Transmission electron microscopy reveals that the Ag nanoparticles with a diameter of about 10 nm are uniformly dispersed along the pillars. The prepared TiO(x)N(y) nanopillar matrix and Ag:TiO(x)N(y) network show strong photocatalytic activity under visible-light irradiation, evaluated via degradation of Rhodamine B 
650 4 |a Journal Article 
700 1 |a Ullah, Najeeb  |e verfasserin  |4 aut 
700 1 |a Divitini, Giorgio  |e verfasserin  |4 aut 
700 1 |a Ducati, Caterina  |e verfasserin  |4 aut 
700 1 |a Kumar, R Vasant  |e verfasserin  |4 aut 
700 1 |a Ding, Yucheng  |e verfasserin  |4 aut 
700 1 |a Barber, Zoe H  |e verfasserin  |4 aut 
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