Microwave-induced synthesis of porous single-crystal-like TiO2 with excellent lithium storage properties

Porous anatase TiO(2) single crystal architectures with large specific surface area and remarkable crystalline phase-stability were fabricated via a green microwave-assisted process. Ionic liquid was chosen as both an essential structure-directing agent for the formation of the {001} facets exposed...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 9 vom: 06. März, Seite 4543-7
1. Verfasser: Zhang, Dieqing (VerfasserIn)
Weitere Verfasser: Wen, Meicheng, Zhang, Peng, Zhu, Jian, Li, Guisheng, Li, Hexing
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Porous anatase TiO(2) single crystal architectures with large specific surface area and remarkable crystalline phase-stability were fabricated via a green microwave-assisted process. Ionic liquid was chosen as both an essential structure-directing agent for the formation of the {001} facets exposed TiO(2) and an etching agent source for selective erosion of the exposed {001} facets, leading to robust porous framework with exposed {101} facets. These porous anatase single crystals were thermally stable up to 800 °C, indicating excellent structure stability. The product showed stable cyclability at high current rate, better reversibility, and high Coulumbic efficiency of 100% for lithium storage 
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700 1 |a Wen, Meicheng  |e verfasserin  |4 aut 
700 1 |a Zhang, Peng  |e verfasserin  |4 aut 
700 1 |a Zhu, Jian  |e verfasserin  |4 aut 
700 1 |a Li, Guisheng  |e verfasserin  |4 aut 
700 1 |a Li, Hexing  |e verfasserin  |4 aut 
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