Highly active platinum nanoparticles on graphene nanosheets with a significant improvement in stability and CO tolerance

© 2012 American Chemical Society

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 8 vom: 28. Feb., Seite 3979-86
1. Verfasser: He, Daping (VerfasserIn)
Weitere Verfasser: Cheng, Kun, Li, Huaiguang, Peng, Tao, Xu, Feng, Mu, Shichun, Pan, Mu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Highly active platinum nanoparticles on graphene nanosheets with a significant improvement in stability and CO tolerance 
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520 |a Graphene nanosheets (GNS) supporting Pt nanoparticles (PNs) are prepared using perfluorosulfonic acid (PFSA) as a functionalization and anchoring agent. Transmission electron microscope (TEM) results indicate that the prepared Pt NPs are uniformly deposited on GNS with a narrow particle size ranging from 1 to 4 nm in diameter. A high catalytic activity of this novel catalyst is observed by both cyclic voltammetry and oxygen reduction reaction (ORR) measurements due to the increasing of proton (H(+)) transmission channels. Significantly, this novel PFSA-functionalized Pt/GNS (PFSA-Pt/GNS) catalyst reveals a better CO oxidation and lower loss rate of electrochemical active area in comparison with that of the plain Pt/GNS and conventional Pt/C catalysts, indicating our PFSA-Pt/GNS catalysts hold much higher stability and CO tolerance by virtue of introduction of PFSA 
650 4 |a Journal Article 
700 1 |a Cheng, Kun  |e verfasserin  |4 aut 
700 1 |a Li, Huaiguang  |e verfasserin  |4 aut 
700 1 |a Peng, Tao  |e verfasserin  |4 aut 
700 1 |a Xu, Feng  |e verfasserin  |4 aut 
700 1 |a Mu, Shichun  |e verfasserin  |4 aut 
700 1 |a Pan, Mu  |e verfasserin  |4 aut 
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