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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la204920b
|2 doi
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|a pubmed24n0715.xml
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|a (DE-627)NLM214470830
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|a (NLM)22235922
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Mugemana, Clément
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Functionalized nanoporous thin films from metallo-supramolecular diblock copolymers
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|c 2012
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 09.07.2012
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|a Date Revised 01.12.2018
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a A polystyrene-[Ni(2+)]-poly(ethylene oxide) metallo-supramolecular block copolymer (PS-[Ni(2+)]-PEO), where -[ is a terpyridine, is used to create nanoporous thin films with free terpyridine ligands homogenously distributed on the pore walls. The PS-[Ni(2+)]-PEO block copolymer is synthesized by a two step assembly process, and is then self-assembled into a thin film in order to obtain PEO cylinders oriented perpendicularly to the film surface. The supramolecular junction is opened by exposing the film to an excess of a competing ligand, and the free PEO block is then rinsed away by a selective solvent. The presence of the terpyridines on the pore walls is evidenced by fluorescence spectroscopy after formation of a fluorescent complex with an europium salt
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Macromolecular Substances
|2 NLM
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|a Membranes, Artificial
|2 NLM
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|a Organometallic Compounds
|2 NLM
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|a Polystyrenes
|2 NLM
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|a Polyethylene Glycols
|2 NLM
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|a 3WJQ0SDW1A
|2 NLM
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|a Nickel
|2 NLM
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|a 7OV03QG267
|2 NLM
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1 |
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|a Gohy, Jean-François
|e verfasserin
|4 aut
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|a Fustin, Charles-André
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 5 vom: 07. Feb., Seite 3018-23
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:28
|g year:2012
|g number:5
|g day:07
|g month:02
|g pages:3018-23
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|u http://dx.doi.org/10.1021/la204920b
|3 Volltext
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