Heterogeneous photo-catalysis system for the degradation of azo dye Reactive Black 5 (RB5)
This study investigated a heterogeneous photo-catalysis system by introducing a novel brick supported iron oxide (denoted as B1) for the heterogeneous photoassisted degradation of Reactive Black 5 (RB5) at pH value from 3 to 7 in a three-phase (gas-liquid-solid) fluidized bed reactor (3P-FBR). Scann...
| Veröffentlicht in: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 65(2012), 2 vom: 01., Seite 221-6 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2012
|
| Zugriff auf das übergeordnete Werk: | Water science and technology : a journal of the International Association on Water Pollution Research |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Coloring Agents Ferric Compounds Naphthalenesulfonates Water Pollutants, Chemical ferric oxide 1K09F3G675 Oxalic Acid 9E7R5L6H31 mehr... |
| Zusammenfassung: | This study investigated a heterogeneous photo-catalysis system by introducing a novel brick supported iron oxide (denoted as B1) for the heterogeneous photoassisted degradation of Reactive Black 5 (RB5) at pH value from 3 to 7 in a three-phase (gas-liquid-solid) fluidized bed reactor (3P-FBR). Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray powder diffraction (XRD) and N(2) adsorption/desorption were used to characterize the B1 catalyst. The in situ formation of hydrogen peroxide and the depletion of oxalic acid by photochemical cycle of Fe(III)-oxalate complex under UVA light (λ = 365 nm) were studied. The effects of the solution pH and the concentration of oxalic acid on the degradation of RB5 are elucidated. About 90% decolourization was measured and 80% of the total organic carbon (TOC) was eliminated at pH 5.0 after 120 min for 20 mg/L RB5 in presence of 10 g/L B1 catalyst, 30 mg/L oxalic acid under 15 W UVA light. A mechanism for the photocatalytic degradation of RB5 over B1 catalyst is proposed |
|---|---|
| Beschreibung: | Date Completed 10.04.2012 Date Revised 25.11.2016 published: Print Citation Status MEDLINE |
| ISSN: | 0273-1223 |
| DOI: | 10.2166/wst.2012.202 |