Synchrotron FTIR microscopy of Langmuir-Blodgett monolayers and polyelectrolyte multilayers at the solid-solid interface

Synchrotron FTIR microscopy has been used to probe the structure of model boundary lubricant layers confined at the solid-solid interface. The combination of high brightness of the IR source and a novel contact geometry that uses a hemispherical internal reflection element as the means for light del...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 3 vom: 24. Jan., Seite 1683-8
1. Verfasser: Beattie, David A (VerfasserIn)
Weitere Verfasser: Beaussart, Audrey, Mierczynska-Vasilev, Agnieszka, Harmer, Sarah L, Thierry, Benjamin, Puskar, Ljiljana, Tobin, Mark
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2012
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Eicosanoic Acids Electrolytes Lubricants Water 059QF0KO0R Hyaluronic Acid 9004-61-9 Chitosan mehr... 9012-76-4 arachidic acid PQB8MJD4RB
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520 |a Synchrotron FTIR microscopy has been used to probe the structure of model boundary lubricant layers confined at the solid-solid interface. The combination of high brightness of the IR source and a novel contact geometry that uses a hemispherical internal reflection element as the means for light delivery has enabled the detection of <2.5 nm thin monolayer lubricant layers in the solid-solid contact, in addition to allowing for spectral acquisition from specific regions of the contact. Spectra of hydration water from within a confined polyelectrolyte multilayer film have also been acquired, highlighting the altered hydrogen bonding environment within the polymer layer 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Mierczynska-Vasilev, Agnieszka  |e verfasserin  |4 aut 
700 1 |a Harmer, Sarah L  |e verfasserin  |4 aut 
700 1 |a Thierry, Benjamin  |e verfasserin  |4 aut 
700 1 |a Puskar, Ljiljana  |e verfasserin  |4 aut 
700 1 |a Tobin, Mark  |e verfasserin  |4 aut 
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