Effect of nanointegration on photoinduced hydrogen-generating nanogel systems
© 2011 American Chemical Society
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 28(2012), 2 vom: 17. Jan., Seite 1539-44 |
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| Weitere Verfasser: | , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Gels Hydrogen 7YNJ3PO35Z |
| Zusammenfassung: | © 2011 American Chemical Society The nanointegration mechanism for photoinduced hydrogen nanogenerators using nanogels is described. By spatially integrating poly(N-isopropylacrylamide-co-Ru(bpy)(3)) nanogels as a photosensitizer and Pt nanoparticles as a catalyst, a mechanism using electrostatic interactions and the shrinking behavior of the thermosensitive polymer network is revealed. In addition, to evaluate the sensitivity to exterior energy, light, and heat, the integrated nanospace is controlled by using thermosensitive nanogels, which drastically shrink above the volume phase transition temperature. Such nanospatial control of multiple kinds of functional molecules in a photochemical reaction is important for the realization of artificial photosynthetic systems |
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| Beschreibung: | Date Completed 01.05.2012 Date Revised 21.11.2013 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la203990n |