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231224s2012 xx |||||o 00| ||eng c |
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|a 10.1021/la203925y
|2 doi
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|a eng
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|a Ortiz, Aurélie U
|e verfasserin
|4 aut
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|a Predicting mixture coadsorption in soft porous crystals
|b experimental and theoretical Study of CO2/CH4 in MIL-53(Al)
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|c 2012
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 25.04.2012
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|a Date Revised 10.01.2012
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a We present a synergistic experimental and theoretical study of CO(2)/CH(4) mixture coadsorption in breathing metal-organic framework MIL-53(Al). Mixture adsorption experiments were performed and their results were analyzed by comparing them to predictions made from pure-component adsorption data using the Osmotic Framework Adsorption Solution Theory (OFAST). This analytical model, fully validated for the first time, was then used to predict coadsorption properties as a function of temperature, pressure, and mixture composition. The phase diagrams obtained show a surprising non-monotonic behavior
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|a Journal Article
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|a Springuel-Huet, Marie-Anne
|e verfasserin
|4 aut
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|a Coudert, François-Xavier
|e verfasserin
|4 aut
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|a Fuchs, Alain H
|e verfasserin
|4 aut
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|a Boutin, Anne
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 28(2012), 1 vom: 10. Jan., Seite 494-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:28
|g year:2012
|g number:1
|g day:10
|g month:01
|g pages:494-8
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|u http://dx.doi.org/10.1021/la203925y
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