A novel technology for on-site cupric oxide recovery from cupric chloride etchant waste

For on-site copper recovery in print circuit board factories, we propose a novel technology to obtain cupric oxide with a low content ratio of chloride from high chloride concentration waste, such as cupric chloride etchant waste. Our technology is designed to avoid formation of double salt and accu...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 64(2011), 2 vom: 11., Seite 416-22
1. Verfasser: Kobayashi, T (VerfasserIn)
Weitere Verfasser: Kano, K, Suzuki, T, Kobayashi, A
Format: Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Water Pollutants, Chemical Copper 789U1901C5 Polychlorinated Biphenyls DFC2HB4I0K cupric chloride S2QG84156O cupric oxide V1XJQ704R4
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245 1 2 |a A novel technology for on-site cupric oxide recovery from cupric chloride etchant waste 
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500 |a Date Revised 18.09.2019 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a For on-site copper recovery in print circuit board factories, we propose a novel technology to obtain cupric oxide with a low content ratio of chloride from high chloride concentration waste, such as cupric chloride etchant waste. Our technology is designed to avoid formation of double salt and accumulation of cupric hydroxide. In the proposed method, etchant waste mixed with hydrogen peroxide solution is added to sodium hydroxide solution by stepwise addition. We performed lab-scale experiments on the influence of reaction pH conditions on the content ratio of chloride in recovering cupric oxide. The results show that recycled cupric oxide tends to contain a lower content ratio of chloride under higher starting temperatures and higher final pH conditions of the reaction. We also confirmed the optimized conditions; the starting temperature of the sodium hydroxide solution is higher than 70 degrees C, and the final pH of the reaction is 11.5 to 12. Based on the optimized temperature and pH conditions, we also performed a pilot trial to recover cupric oxide from real etchant waste. Then, we successfully obtained cupric oxide with a content ratio of chloride in 80 mg-Cl/kg-CuO 
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650 7 |a Copper  |2 NLM 
650 7 |a 789U1901C5  |2 NLM 
650 7 |a Polychlorinated Biphenyls  |2 NLM 
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650 7 |a cupric chloride  |2 NLM 
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650 7 |a cupric oxide  |2 NLM 
650 7 |a V1XJQ704R4  |2 NLM 
700 1 |a Kano, K  |e verfasserin  |4 aut 
700 1 |a Suzuki, T  |e verfasserin  |4 aut 
700 1 |a Kobayashi, A  |e verfasserin  |4 aut 
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