Effect of film thickness and filler properties on sulphuric acid permeation in various commercially available epoxy mortar coatings

The performance of various commercially available epoxy mortar coatings was compared by measuring their sulphuric acid diffusivity. Apparent diffusivities, which were measured gravimetrically, were found to be dependent on coating tortuosity. In composite materials like epoxy mortars, the tortuosity...

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Détails bibliographiques
Publié dans:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 64(2011), 9 vom: 31., Seite 1864-9
Auteur principal: Valix, M (Auteur)
Autres auteurs: Mineyama, H, Chen, C, Cheung, W H, Shi, J, Bustamante, H
Format: Article en ligne
Langue:English
Publié: 2011
Accès à la collection:Water science and technology : a journal of the International Association on Water Pollution Research
Sujets:Journal Article Epoxy Compounds Polymers Sulfuric Acids sulfuric acid O40UQP6WCF
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520 |a The performance of various commercially available epoxy mortar coatings was compared by measuring their sulphuric acid diffusivity. Apparent diffusivities, which were measured gravimetrically, were found to be dependent on coating tortuosity. In composite materials like epoxy mortars, the tortuosity was determined by filler properties and polymer alignment. Tortuosity was found to depend on the filler size, their dispersion, filler aspect ratio and concentration. The order and greater alignment of polymer aggregates, which characterises thinner coatings effects higher tortuosity and thus lower permeabilities. The result is that sulphuric acid diffusivities were observed to increase with coating thickness, which challenges the notion that greater coating thicknesses provide greater protection or environmental barrier. The effect of film thickness and filler properties observed in this study has significant implications to the current selection of coatings and sewer protection 
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700 1 |a Shi, J  |e verfasserin  |4 aut 
700 1 |a Bustamante, H  |e verfasserin  |4 aut 
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