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231224s2011 xx |||||o 00| ||eng c |
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|a 10.1107/S0909049511036326
|2 doi
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|a eng
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|a Wang, Ling
|e verfasserin
|4 aut
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|a Titanium local structure in tektite probed by X-ray absorption fine structure spectroscopy
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|c 2011
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 08.02.2012
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|a Date Revised 14.10.2011
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The local structure of titanium in tektites from six strewn fields was studied by Ti K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) in order to provide quantitative data on Ti-O distance and Ti coordination number. The titanium in tektites possessed different coordination environment types. XANES spectra patterns revealed resemblance to high-temperature TiO(2)-SiO(2) glass and TiO(2) anatase. All samples showed that the valence of Ti is 4+. Based on the Ti-O distances, coordination numbers and radial distribution function determined by EXAFS analyses, the tektites were classified into three types: type I, Ti occupies a four-coordinated tetrahedral site with Ti-O distances of 1.84-1.79 Å; type II, Ti occupies a five-coordinated trigonal bipyramidal or tetragonal pyramidal site with Ti-O distances of 1.92-1.89 Å; type III, Ti occupies a six-coordinated octahedral site with Ti-O distances of 2.00-1.96 Å. Although Ti occupies the TiO(6) octahedral site in most titanium minerals under ambient conditions, some tektites have four- and five-coordinated Ti. This study indicated that the local structure of Ti might change in impact events and the following stages
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|a Journal Article
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|a Yoshiasa, Akira
|e verfasserin
|4 aut
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|a Okube, Maki
|e verfasserin
|4 aut
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|a Takeda, Takashi
|e verfasserin
|4 aut
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|i Enthalten in
|t Journal of synchrotron radiation
|d 1994
|g 18(2011), Pt 6 vom: 04. Nov., Seite 885-90
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|x 1600-5775
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|g volume:18
|g year:2011
|g number:Pt 6
|g day:04
|g month:11
|g pages:885-90
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|u http://dx.doi.org/10.1107/S0909049511036326
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|d 18
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