Titanium local structure in tektite probed by X-ray absorption fine structure spectroscopy

The local structure of titanium in tektites from six strewn fields was studied by Ti K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) in order to provide quantitative data on Ti-O distance and Ti coordination number. The titanium in tektites po...

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Veröffentlicht in:Journal of synchrotron radiation. - 1994. - 18(2011), Pt 6 vom: 04. Nov., Seite 885-90
1. Verfasser: Wang, Ling (VerfasserIn)
Weitere Verfasser: Yoshiasa, Akira, Okube, Maki, Takeda, Takashi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Journal of synchrotron radiation
Schlagworte:Journal Article
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520 |a The local structure of titanium in tektites from six strewn fields was studied by Ti K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) in order to provide quantitative data on Ti-O distance and Ti coordination number. The titanium in tektites possessed different coordination environment types. XANES spectra patterns revealed resemblance to high-temperature TiO(2)-SiO(2) glass and TiO(2) anatase. All samples showed that the valence of Ti is 4+. Based on the Ti-O distances, coordination numbers and radial distribution function determined by EXAFS analyses, the tektites were classified into three types: type I, Ti occupies a four-coordinated tetrahedral site with Ti-O distances of 1.84-1.79 Å; type II, Ti occupies a five-coordinated trigonal bipyramidal or tetragonal pyramidal site with Ti-O distances of 1.92-1.89 Å; type III, Ti occupies a six-coordinated octahedral site with Ti-O distances of 2.00-1.96 Å. Although Ti occupies the TiO(6) octahedral site in most titanium minerals under ambient conditions, some tektites have four- and five-coordinated Ti. This study indicated that the local structure of Ti might change in impact events and the following stages 
650 4 |a Journal Article 
700 1 |a Yoshiasa, Akira  |e verfasserin  |4 aut 
700 1 |a Okube, Maki  |e verfasserin  |4 aut 
700 1 |a Takeda, Takashi  |e verfasserin  |4 aut 
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