Comparison of Fenton's oxidation and ozonation for removal of estrogens

This study compares efficiency of Fenton's oxidation and ozonation of 17beta-estradiol (E2) and 17alpha-ethinylestradiol (EE2) as two possible processes for removal of estrogens from aqueous solutions. The effectiveness of Fenton's oxidative removal was studied at different ratios of reage...

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Bibliographische Detailangaben
Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 63(2011), 10 vom: 07., Seite 2131-7
1. Verfasser: Nakrst, Jana (VerfasserIn)
Weitere Verfasser: Bistan, Mirjana, Tisler, Tatjana, Zagorc-Koncan, Jana, Derco, Jan, Gotvajn, Andreja Zgajnar
Format: Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Comparative Study Journal Article Fenton's reagent Water Pollutants, Chemical Ethinyl Estradiol 423D2T571U Estradiol 4TI98Z838E Ozone 66H7ZZK23N mehr... Hydrogen Peroxide BBX060AN9V Iron E1UOL152H7
Beschreibung
Zusammenfassung:This study compares efficiency of Fenton's oxidation and ozonation of 17beta-estradiol (E2) and 17alpha-ethinylestradiol (EE2) as two possible processes for removal of estrogens from aqueous solutions. The effectiveness of Fenton's oxidative removal was studied at different ratios of reagents Fe2+:H2O2 (1:0.5; 1:10; 1:20; 1:33), where with some molar ratios up to 100% removal of E2 and EE2 was achieved in the first few minutes of reaction. The best molar ratio for E2 (17beta-estradiol) removal was 1:33, while in the case of EE2 the most efficient one was 1:20 ratio. Ozonation was much faster, because complete removal of estrogens was achieved in 30 seconds (pH approximately eaqual 6), but the time of ozonation was extended up to 60 minutes trying to decompose formed by-products, expressing estrogenic activity, detected by YES (Yeast Estrogen Screening) assay. The obtained results showed that the removal efficiency of estrogens from waters should be assessed by a combination of chemical analyses and bioassay
Beschreibung:Date Completed 07.11.2011
Date Revised 18.09.2019
published: Print
Citation Status MEDLINE
ISSN:0273-1223