|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM211674141 |
| 003 |
DE-627 |
| 005 |
20250213061419.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2011 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la202978d
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n0705.xml
|
| 035 |
|
|
|a (DE-627)NLM211674141
|
| 035 |
|
|
|a (NLM)21939277
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Kycia, Annia H
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Electrochemical and STM studies of 1-thio-β-D-glucose self-assembled on a Au(111) electrode surface
|
| 264 |
|
1 |
|c 2011
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 16.02.2012
|
| 500 |
|
|
|a Date Revised 21.11.2013
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a In this study, a Au(111) electrode is functionalized with a monolayer of 1-thio-β-D-glucose (β-Tg), producing a hydrophilic surface. A monolayer of β-Tg was formed on a Au(111) surface by either (1) potential-assisted deposition with the thiol in a supporting electrolyte or (2) passive incubation of a gold substrate in a thiol-containing solution. For each method, the properties of the β-Tg monolayer were investigated using cyclic voltammetry (CV), differential capacitance (DC), and chronocoulometry. In addition, electrochemical scanning tunneling microscopy (EC-STM) was used to obtain images of the self-assembled monolayer with molecular resolution. Potential-assisted assembly of β-Tg onto a Au(111) electrode surface was found to be complicated by oxidation of β-Tg molecules. The EC-STM images revealed formation of a passive layer containing honeycomb-like domains characteristic of a formation of S(8) rings, indicating the S-C bond may have been cleaved. In contrast, passive self-assembly of thioglucose from a methanol solution was found to produce a stable, disordered monolayer of β-Tg. Since the passive assembly method was not complicated by the presence of a faradaic process, it is the method of choice for modifying the gold surface with a hydrophilic monolayer
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 650 |
|
7 |
|a Electrolytes
|2 NLM
|
| 650 |
|
7 |
|a Gold
|2 NLM
|
| 650 |
|
7 |
|a 7440-57-5
|2 NLM
|
| 650 |
|
7 |
|a 1-thioglucose
|2 NLM
|
| 650 |
|
7 |
|a 7534-35-2
|2 NLM
|
| 650 |
|
7 |
|a Glucose
|2 NLM
|
| 650 |
|
7 |
|a IY9XDZ35W2
|2 NLM
|
| 700 |
1 |
|
|a Sek, Slawomir
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Su, Zhangfei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Merrill, A Rod
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lipkowski, Jacek
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 27(2011), 21 vom: 01. Nov., Seite 13383-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:27
|g year:2011
|g number:21
|g day:01
|g month:11
|g pages:13383-9
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la202978d
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 27
|j 2011
|e 21
|b 01
|c 11
|h 13383-9
|