Advanced oxidation processes for treatment of effluents from a detergent industry

Ozonation, catalytic ozonation, Fenton's and heterogeneous Fenton-like processes were investigated as possible pretreatments of a low biodegradable and highly toxic wastewater produced by a detergent industry. The presence of a Mn-Ce-O catalyst in ozonation enhances the biodegradability and imp...

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Détails bibliographiques
Publié dans:Environmental technology. - 1993. - 32(2011), 9-10 vom: 23. Juli, Seite 1031-41
Auteur principal: Martins, Rui C (Auteur)
Autres auteurs: Silva, Adrián M T, Castro-Silva, Sérgio, Garção-Nunes, Paulo, Quinta-Ferreira, Rosa M
Format: Article
Langue:English
Publié: 2011
Accès à la collection:Environmental technology
Sujets:Journal Article Research Support, Non-U.S. Gov't Detergents Fenton's reagent Industrial Waste Water Pollutants, Chemical Hydrogen Peroxide BBX060AN9V Iron E1UOL152H7 plus... Oxygen S88TT14065
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520 |a Ozonation, catalytic ozonation, Fenton's and heterogeneous Fenton-like processes were investigated as possible pretreatments of a low biodegradable and highly toxic wastewater produced by a detergent industry. The presence of a Mn-Ce-O catalyst in ozonation enhances the biodegradability and improves the degradation at low pH values. However, a high content of carbonyl compounds adsorbed on the recovered solid indicates some limitations for real-scale application. A commercial Fe2O3-MnOx catalyst shows higher activity as well as higher stability concerning carbon adsorption, but the leaching of metals is larger than for Mn-Ce-O. Regarding the heterogeneous Fenton-like route with an Fe-Ce-O catalyst, even though a high activity and stability are attained, the intermediates are less biodegradable than the original compounds, indicating that the resulting effluent cannot be conducted to an activated sludge post-treatment. The highest enhancement of effluent biodegradability is obtained with the classic homogeneous Fenton's process, with the BOD5/COD ratio increasing from 0.32 to 0.80. This process was scaled up and the treated effluent is now safely directed to a municipal wastewater treatment plant 
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700 1 |a Quinta-Ferreira, Rosa M  |e verfasserin  |4 aut 
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