Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride

Reinvestigation of the Lewis acid catalyzed rearrangement of some open-chain permethyloligosilanes with the Al(Fe)Cl(3) catalyst system exhibited several cases of additional reactivity: namely, a fragmentation/cyclization reaction. Introduction of (trimethylsilyl)methyl substituents into the oligosi...

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Publié dans:Organometallics. - 1998. - 30(2011), 15 vom: 08. Aug., Seite 3939-3954
Auteur principal: Wagner, Harald (Auteur)
Autres auteurs: Baumgartner, Judith, Marschner, Christoph, Poelt, Peter
Format: Article
Langue:English
Publié: 2011
Accès à la collection:Organometallics
Sujets:Journal Article