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231224s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la201306a
|2 doi
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|a eng
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1 |
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|a Fang, Guanjiu
|e verfasserin
|4 aut
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|a Photodegradation of azobenzene-based self-assembled monolayers characterized by in-plane birefringence
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 29.12.2011
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|a Date Revised 15.11.2012
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a © 2011 American Chemical Society
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|a Azobenzene-based self-assembled monolayers (azo-SAMs) are photoactive and become orientationally ordered when illuminated with linearly polarized light (LPL), making them attractive as dynamic alignment layers in liquid crystal cells. Azo-SAMs, however, are chemically unstable when exposed to both air and light. We have characterized the photodegradation of a methyl red-based SAM by measuring with a high-sensitivity polarimeter the optical anisotropy induced by illumination with linearly polarized actinic light after the sample is irradiated with circularly polarized light (CPL) in air. The number of unbleached, photoactive molecules in the SAM decays exponentially with CPL exposure time, lowering the reorientation rate during photowriting with LPL. Azo-SAMs in an argon atmosphere, in contrast, are chemically stable and remain photoactive even after exposure to CPL
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|a Journal Article
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a Azo Compounds
|2 NLM
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|a Membranes, Artificial
|2 NLM
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|a azobenzene
|2 NLM
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| 650 |
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|a F0U1H6UG5C
|2 NLM
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1 |
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|a Shi, Yue
|e verfasserin
|4 aut
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|a Maclennan, Joseph E
|e verfasserin
|4 aut
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1 |
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|a Walba, David M
|e verfasserin
|4 aut
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|a Clark, Noel A
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 17 vom: 06. Sept., Seite 10407-11
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:27
|g year:2011
|g number:17
|g day:06
|g month:09
|g pages:10407-11
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|u http://dx.doi.org/10.1021/la201306a
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