Host-guest interactions between a nonmicellized amphiphilic invertible polymer and insoluble cyclohexasilane in acetonitrile
© 2011 American Chemical Society
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 27(2011), 17 vom: 06. Sept., Seite 10356-9 |
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| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2011
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, U.S. Gov't, Non-P.H.S. Acetonitriles Decanoic Acids Dicarboxylic Acids Silanes Polyethylene Glycols 3WJQ0SDW1A sebacic acid 97AN39ICTC mehr... |
| Zusammenfassung: | © 2011 American Chemical Society Host-guest interactions between cyclohexasilane (Si(6)H(12)) and amphiphilic invertible macromolecules based on PEG and sebacic acid in acetonitrile (neither a solvent for cyclohexasilane nor a support for the micellization of amphiphilic invertible macromolecules) have been investigated. Despite the extended conformation of the macromolecules and the absence of self-assembled polymeric domains, a macromolecular amphiphilicity itself contributes to localizing Si(6)H(12) by AIP and thus enables Lewis acid-base interactions between Si(6)H(12) and the AIP carbonyl groups. The obtained results demonstrate an interesting phenomenon in that insoluble Si(6)H(12) can be localized by AIP macromolecules in a medium that does not support the formation of polymeric domains |
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| Beschreibung: | Date Completed 29.12.2011 Date Revised 01.12.2018 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la201883f |