Synthesis and characterization of pillared stevensites : application to chromate adsorption

The purpose of this work was to study the synthesis of pillared interlayered clays from Moroccan stevensite called locally 'Ghassoul'. This clay has been intercalated with cetyltrimethylammonium surfactant (CTA-Stv) and aluminium hydroxypolycation (Al13-Stv). Characterization studies were...

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Veröffentlicht in:Environmental technology. - 1998. - 32(2011), 3-4 vom: 21. Feb., Seite 363-72
1. Verfasser: Benhammou, A (VerfasserIn)
Weitere Verfasser: Yaacoubi, A, Nibou, L, Bonnet, J P, Tanouti, B
Format: Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Aluminum Silicates Cetrimonium Compounds Chromates Surface-Active Agents Water Pollutants, Chemical Aluminum CPD4NFA903 Clay mehr... T1FAD4SS2M Cetrimonium Z7FF1XKL7A
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245 1 0 |a Synthesis and characterization of pillared stevensites  |b application to chromate adsorption 
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520 |a The purpose of this work was to study the synthesis of pillared interlayered clays from Moroccan stevensite called locally 'Ghassoul'. This clay has been intercalated with cetyltrimethylammonium surfactant (CTA-Stv) and aluminium hydroxypolycation (Al13-Stv). Characterization studies were performed using XRF, XRD, FTIR and DTA/TG analysis. Basal spacing values of Al13-Stv and CTA-Stv increased respectively from 13.5 A for natural stevensite to 17.5 and 17.6 A with increasing Al13(7+)/clay and CTA+/clay ratios. The DTA/TG results showed that Al13-Stv has a relatively high thermal stability compared with CTA-Stv. A quasi-irreversible intercalation by exchanging the interlayer inorganic cations with voluminous pillars Al13(7+) or CTA+ was observed. Batch adsorption of chromate anions from aqueous solutions was investigated and the results showed that both pillared clays had great affinity for the chromate compared with untreated stevensite. The Dubinin-Kaganer-Radushkevich (DKR) model was selected to describe the adsorption isotherms. The maximum adsorption capacities for natural stevensite, Al13-Stv and CTA-Stv are 13.7, 75.4 and 195.6 mmol/kg, respectively 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Cetrimonium Compounds  |2 NLM 
650 7 |a Chromates  |2 NLM 
650 7 |a Surface-Active Agents  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Aluminum  |2 NLM 
650 7 |a CPD4NFA903  |2 NLM 
650 7 |a Clay  |2 NLM 
650 7 |a T1FAD4SS2M  |2 NLM 
650 7 |a Cetrimonium  |2 NLM 
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700 1 |a Yaacoubi, A  |e verfasserin  |4 aut 
700 1 |a Nibou, L  |e verfasserin  |4 aut 
700 1 |a Bonnet, J P  |e verfasserin  |4 aut 
700 1 |a Tanouti, B  |e verfasserin  |4 aut 
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