Single-walled carbon nanotube/pyrenecyclodextrin nanohybrids for ultrahighly sensitive and selective detection of p-nitrophenol

Electrochemical detection of p-nitrophenol (P-NP) using a highly sensitive and selective platform based on single-walled carbon nanotube/pyrenecyclodextrin (SWCNT/PyCD) nanohybrids is described for the first time. The electrochemical performance of the SWCNT/PyCD nanohybrid electrode was fully compa...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 16 vom: 16. Aug., Seite 10295-301
1. Verfasser: Wei, Yan (VerfasserIn)
Weitere Verfasser: Kong, Ling-Tao, Yang, Ran, Wang, Lun, Liu, Jin-Huai, Huang, Xing-Jiu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Electrochemical detection of p-nitrophenol (P-NP) using a highly sensitive and selective platform based on single-walled carbon nanotube/pyrenecyclodextrin (SWCNT/PyCD) nanohybrids is described for the first time. The electrochemical performance of the SWCNT/PyCD nanohybrid electrode was fully compared with bare glassy carbon, single-SWCNT, single-PyCD, and SWCNT/CD (without pyrene rings) electrodes. Besides the techniques of cyclic voltammetry and chronoamperometric transients, differential pulse voltammetry (DPV) has been used for the detection of P-NP without any interference from o-nitrophenol (O-NP) at the potentials of -0.80 and -0.67 V, respectively. The SWCNT/PyCD nanohybrid electrode is highly sensitive, and it shows an ultrahigh sensitivity of 18.7 μA/μM toward P-NP in contrast to the values reported previously. The detection limit (S/N = 3) of the SWCNT/PyCD nanohybrid electrode toward P-NP is 0.00086 μM (0.12 ppb), which is well below the allowed limit in drinking water, 0.43 μM, given by the U.S. Environmental Protection Agency (EPA). The analytical performance of the SWCNT/PyCD nanohybrid electrode toward P-NP is superior to the existing electrodes 
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700 1 |a Kong, Ling-Tao  |e verfasserin  |4 aut 
700 1 |a Yang, Ran  |e verfasserin  |4 aut 
700 1 |a Wang, Lun  |e verfasserin  |4 aut 
700 1 |a Liu, Jin-Huai  |e verfasserin  |4 aut 
700 1 |a Huang, Xing-Jiu  |e verfasserin  |4 aut 
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