Strong inclusion of inorganic anions into β-cyclodextrin immobilized to gold electrode
© 2011 American Chemical Society
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 17 vom: 06. Sept., Seite 10580-6 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2011
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Anions Nitrates Phosphates Sulfates beta-Cyclodextrins Gold 7440-57-5 betadex JV039JZZ3A |
| Zusammenfassung: | © 2011 American Chemical Society The inclusion of inorganic anions such as SO(4)(2-), NO(3)(-), and HPO(4)(2-) into the cavity of β-cyclodextrin monolayers on Au was examined by X-ray photoelectron spectroscopy (XPS), a quartz crystal microbalance (QCM), and chronocoulometric measurements of the competitive inclusion with ferrocene. The inclusion amounts of ferrocence in 0.2 M Na(2)SO(4), NaNO(3), and Na(2)HPO(4) solutions were less than 6% of the adsorption amount of β-cyclodextrin on Au, resulting in the apparent inhibition of the ferrocene redox reaction. The surface association constants of these anions reached about 10 on a logarithmic scale and were much higher than those for the inclusion of common organic guest compounds. A stronger anion inclusion was also demonstrated by the QCM response corresponding to the replacement of a preincluded organic guest with sulfate upon the injection of the sulfate solution. Quantitative analysis of the XPS data suggested a 1:1 association for each of these anions per surface β-cyclodextrin. There was no detectable inclusion for ClO(4)(-), Cl(-), and Br(-) |
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| Beschreibung: | Date Completed 29.12.2011 Date Revised 15.11.2012 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la1051063 |