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231224s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la201261r
|2 doi
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|a eng
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|a Stefanopoulos, Konstantinos L
|e verfasserin
|4 aut
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|a Investigation of confined ionic liquid in nanostructured materials by a combination of SANS, contrast-matching SANS, and nitrogen adsorption
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 18.10.2011
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|a Date Revised 29.06.2011
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2011 American Chemical Society
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|a Small-angle neutron scattering (SANS), contrast-matching SANS, and nitrogen adsorption have been utilized to investigate the confined ionic liquid (IL) [bmim][PF(6)] phase in ordered mesoporous silica MCM-41 and SBA-15. The results suggest that the pores of SBA-15 are completely filled with IL whereas a small fraction of the pore volume, the pore "core", of MCM-41 is empty. The contrast-matching SANS measurements confirm the enhanced solubility of water in IL. In addition, they provide strong evidence that water does not enter the empty pore core of MCM-41, possibly because of the preferred orientation of the IL molecules in the adsorbed layer
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|a Journal Article
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|a Romanos, George E
|e verfasserin
|4 aut
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1 |
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|a Vangeli, Olga C
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Mergia, Konstantina
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kanellopoulos, Nick K
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Koutsioubas, Alexandros
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lairez, Didier
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 27(2011), 13 vom: 05. Juli, Seite 7980-5
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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| 773 |
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|g volume:27
|g year:2011
|g number:13
|g day:05
|g month:07
|g pages:7980-5
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|u http://dx.doi.org/10.1021/la201261r
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