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231224s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la2012809
|2 doi
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|a pubmed24n0693.xml
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|a (NLM)21548624
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|a DE-627
|b ger
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|e rakwb
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|a eng
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|a Gujrati, Maneesh D
|e verfasserin
|4 aut
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|a Luminescent charge-transfer complexes
|b tuning emission in binary fluorophore mixtures
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 23.09.2011
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|a Date Revised 15.11.2012
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Charge-transfer (CT) complexes composed of a π-electron-poor naphthalene diimide (NDI) derivative combined with a series of π-electron-rich donors were investigated. Solutions of the CT complexes are nonemissive; however, solid-state complexes and aqueous suspensions display emission that is dependent on the energy of the HOMO of the electron donor. Crystallographic analysis of a pyrene-NDI complex reveals columnar packing and a high degree of frontier molecular orbital (FMO) overlap that likely contributes to the observed optical properties. The fluorescent CT particles are utilized as imaging agents; additional luminescent CT complexes may be realized by considering FMO energies and topologies
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|a Journal Article
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|a Fluorescent Dyes
|2 NLM
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|a Naphthalenes
|2 NLM
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|a Pyrenes
|2 NLM
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|a naphthalene
|2 NLM
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|a 2166IN72UN
|2 NLM
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|a pyrene
|2 NLM
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|a 9E0T7WFW93
|2 NLM
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|a Kumar, N S Saleesh
|e verfasserin
|4 aut
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|a Brown, Adrienne S
|e verfasserin
|4 aut
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|a Captain, Burjor
|e verfasserin
|4 aut
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|a Wilson, James N
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 11 vom: 07. Juni, Seite 6554-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:27
|g year:2011
|g number:11
|g day:07
|g month:06
|g pages:6554-8
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|u http://dx.doi.org/10.1021/la2012809
|3 Volltext
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