Degradation mechanism of Methyl Orange by electrochemical process on RuO(x)-PdO/Ti electrode
The electrochemical degradation of Methyl Orange in 0.1 M NaCl solution over RuO(x)-PdO/Ti anode was investigated. Chemical oxygen demand (COD), ion chromatography (IC), Fourier Transform Infrared Spectroscopy (FTIR) and Gas chromatography-mass spectrometry (GC-MS) were employed to detect the interm...
| Veröffentlicht in: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 63(2011), 7 vom: 17., Seite 1539-45 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2011
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| Zugriff auf das übergeordnete Werk: | Water science and technology : a journal of the International Association on Water Pollution Research |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Azo Compounds Coloring Agents Ruthenium Compounds Water Pollutants, Chemical Palladium 5TWQ1V240M methyl orange 6B4TC34456 mehr... |
| Zusammenfassung: | The electrochemical degradation of Methyl Orange in 0.1 M NaCl solution over RuO(x)-PdO/Ti anode was investigated. Chemical oxygen demand (COD), ion chromatography (IC), Fourier Transform Infrared Spectroscopy (FTIR) and Gas chromatography-mass spectrometry (GC-MS) were employed to detect the intermediates formed during the electrochemical degradation. In the present reaction system, Methyl Orange could be effectively degraded. After 1 h treatment, the discoloration could reach 97.9% with COD removal of 57.6%. The results indicated that in the presence of chloride, the electrolysis was able to oxidise the dye with partial mineralisation of carbon, nitrogen and sulfur into CO(2), NO(-)(3) and SO(2-)(4), respectively. After 8 h electrolysis, 62% of sulfur contained in Methyl Orange was transformed to SO(4)(2-), and 17.6% of nitrogen changed to NO(3)(-). The intermediates during electroprocess were detected to be low molecular weight compounds, chlorinated compounds, derivatives of benzene and long chain alkanes. Based on these data, a possible degradation mechanism of Methyl Orange was proposed |
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| Beschreibung: | Date Completed 14.07.2011 Date Revised 25.11.2016 published: Print Citation Status MEDLINE |
| ISSN: | 0273-1223 |
| DOI: | 10.2166/wst.2011.414 |