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231224s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la1050767
|2 doi
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|a pubmed24n0689.xml
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|a eng
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| 100 |
1 |
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|a Strojnik, Martin
|e verfasserin
|4 aut
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|a Ionization energy and energy gap structure of MoSI molecular wires
|b Kelvin probe, ultraviolet photoelectron spectroscopy, and cyclic voltammetry measurements
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 26.08.2011
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|a Date Revised 12.04.2011
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2011 American Chemical Society
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|a The work function W of Mo(6)S(3)I(6) molecular nanowires is determined by Kelvin probe (KP) measurements, UV photoelectron spectroscopy (UPS), and cyclic voltammetry (CV). The values obtained by all three methods agree well, giving W = 4.8 ± 0.1 eV. CV measurements also give a gap between the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of E(g) = 1.2 ± 0.1 eV, in agreement with recent optical measurements, but in disagreement with theoretical calculations, which predict the material to be a metal. The electronic structure of Mo(6)S(3)I(6) suggests use of the material in applications such as bulk heterostructure photovoltaics and transparent electrodes and for molecular electronics devices
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|a Journal Article
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|a Omerzu, Ales
|e verfasserin
|4 aut
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|a Majkić, Aleksej
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Mihailovic, Peter M
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lukan, Junos
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Bavdek, Gregor
|e verfasserin
|4 aut
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1 |
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|a Bratina, Gvido
|e verfasserin
|4 aut
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| 700 |
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|a Cvetko, Dean
|e verfasserin
|4 aut
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1 |
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|a Topolovsek, Peter
|e verfasserin
|4 aut
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| 700 |
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|a Mihailovic, Dragan
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 27(2011), 8 vom: 19. Apr., Seite 4296-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:27
|g year:2011
|g number:8
|g day:19
|g month:04
|g pages:4296-9
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|u http://dx.doi.org/10.1021/la1050767
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