Effects of operational parameters on decolorisation of C.I. Reactive Black 5 in UV/TiO(2) system

This study utilises a UV/TiO(2) system to decolorise C.I. Reactive Black 5 (RB5). The effects of TiO(2) dosage, pH, RB5 concentration and light power on the decolorisation efficiency using the UV/TiO(2) system were determined. IO(4)(-) was employed as an oxidant to increase the photodegradation effi...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 63(2011), 5 vom: 29., Seite 1032-6
1. Verfasser: Wu, C H (VerfasserIn)
Weitere Verfasser: Kuo, C Y, Hong, P K A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Coloring Agents Naphthalenesulfonates Water Pollutants, Chemical Periodic Acid 10450-60-9 titanium dioxide 15FIX9V2JP metaperiodate mehr... B45A1BUM4Q Titanium D1JT611TNE Remazol black B O0HDY58362
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500 |a Date Revised 25.11.2016 
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520 |a This study utilises a UV/TiO(2) system to decolorise C.I. Reactive Black 5 (RB5). The effects of TiO(2) dosage, pH, RB5 concentration and light power on the decolorisation efficiency using the UV/TiO(2) system were determined. IO(4)(-) was employed as an oxidant to increase the photodegradation efficiency of UV/TiO(2). The decolorisation rate constants (k) of RB5 in the UV/TiO(2) system are consistent with pseudo-first-order kinetics. The k values of 0.1, 0.5, 1.0 and 2.0 g/l TiO(2) were 0.53, 0.52, 0.69 and 0.68 h(-1), respectively. The rate constant increases with decreasing pH from 10 to 4. The decolorisation rate approximates linear relationship with RB5 concentration, as given by k=1.05[1/RB5](0.98); it varies nonlinearly with light power, as given by k=0.178[power](0.63). The experimental results reveal that the rate of decolorisation obtained using UV/TiO(2)/IO(4)(-) exceeds that obtained using UV/TiO(2) 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Periodic Acid  |2 NLM 
650 7 |a 10450-60-9  |2 NLM 
650 7 |a titanium dioxide  |2 NLM 
650 7 |a 15FIX9V2JP  |2 NLM 
650 7 |a metaperiodate  |2 NLM 
650 7 |a B45A1BUM4Q  |2 NLM 
650 7 |a Titanium  |2 NLM 
650 7 |a D1JT611TNE  |2 NLM 
650 7 |a Remazol black B  |2 NLM 
650 7 |a O0HDY58362  |2 NLM 
700 1 |a Kuo, C Y  |e verfasserin  |4 aut 
700 1 |a Hong, P K A  |e verfasserin  |4 aut 
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773 1 8 |g volume:63  |g year:2011  |g number:5  |g day:29  |g pages:1032-6 
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