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231223s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la200199b
|2 doi
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|a pubmed24n0688.xml
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|a eng
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|a Hoshi, Nagahiro
|e verfasserin
|4 aut
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|a Surface X-ray scattering of stepped surfaces of platinum in an electrochemical environment
|b Pt(331) = 3(111)-(111) and Pt(511) = 3(100)-(111)
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 13.07.2011
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|a Date Revised 30.03.2011
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Real surface structures of the high-index planes of Pt with three atomic rows of terraces (Pt(331) = 3(111)-(111) and Pt(511) = 3(100)-(111)) have been determined in 0.1 M HClO(4) at 0.1 and 0.5 V(RHE) with the use of surface X-ray scattering (SXS). The surfaces with two atomic rows of terraces, Pt(110) = 2(111)-(111) and Pt(311) = 2(100)-(111) = 2(111)-(100), are reconstructed to a (1 × 2) structure according to previous studies. However, the surfaces with three atomic rows of terraces have pseudo-(1 × 1) structures. The interlayer spacing between the first and the second layers, d(12), is expanded 13% on Pt(331) compared to that of the bulk, whereas it is contracted 37% on Pt(511). The surface structures do not depend on the applied potential on either surface
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|a Journal Article
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|a Nakamura, Masashi
|e verfasserin
|4 aut
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|a Sakata, Osami
|e verfasserin
|4 aut
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|a Nakahara, Akira
|e verfasserin
|4 aut
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|a Naito, Keita
|e verfasserin
|4 aut
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|a Ogata, Hiroyuki
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 7 vom: 05. Apr., Seite 4236-42
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:27
|g year:2011
|g number:7
|g day:05
|g month:04
|g pages:4236-42
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|u http://dx.doi.org/10.1021/la200199b
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