Tunable wetting mechanism of polypyrrole surfaces and low-voltage droplet manipulation via redox

This paper presents the experimental results and analyses on a controlled manipulation of liquid droplets upon local reduction and oxidation (redox) of a smart polymer-dodecylbenzenesulfonate doped polypyrrole (PPy(DBS)). The electrochemically tunable wetting property of PPy(DBS) permitted liquid dr...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 7 vom: 05. Apr., Seite 4249-56
1. Verfasser: Tsai, Yao-Tsan (VerfasserIn)
Weitere Verfasser: Choi, Chang-Hwan, Gao, Ning, Yang, Eui-Hyeok
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S. Polymers Pyrroles polypyrrole 30604-81-0 Methylene Chloride 588X2YUY0A
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520 |a This paper presents the experimental results and analyses on a controlled manipulation of liquid droplets upon local reduction and oxidation (redox) of a smart polymer-dodecylbenzenesulfonate doped polypyrrole (PPy(DBS)). The electrochemically tunable wetting property of PPy(DBS) permitted liquid droplet manipulation at very low voltages (-0.9 to 0.6 V). A dichloromethane (DCM) droplet was flattened upon PPy(DBS) reduction. It was found that the surface tension gradient across the droplet contact line induced Marangoni stress, which caused this deformation. Further observation of PPy(DBS)'s color change upon the redox process confirmed that the surface tension gradient was the driving force for the droplet shape change 
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650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
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700 1 |a Choi, Chang-Hwan  |e verfasserin  |4 aut 
700 1 |a Gao, Ning  |e verfasserin  |4 aut 
700 1 |a Yang, Eui-Hyeok  |e verfasserin  |4 aut 
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