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231223s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la104527b
|2 doi
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|a pubmed24n0687.xml
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|a (DE-627)NLM206121415
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|a (NLM)21348504
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Lomoschitz, Christoph J
|e verfasserin
|4 aut
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|a Directing alkyl chain ordering of functional phosphorus coupling agents on ZrO2
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 13.07.2011
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a ZrO(2) powder (6.6 m(2)/g) was modified using polymerizable phosphorus-based coupling agents (P-CAs) (i.e., phosphonic acid, phosphoric acid, and bis-phosphonic acid), resulting in densely grafted layers as determined by thermogravimetry and elemental analysis (up to 4.2 molecules/nm(2)). The applied P-CAs contained a methacrylate group, which led to the covalent incorporation of a polymerizable moiety into the grafted layer. To direct the ordering of the alkyl chains in the layer, three different approaches were evaluated with respect to their structure-directing ability by means of FT-IR and nitrogen sorption at 77 K: (i) variation of the chain length, (ii) variation of the anchoring group and (iii) comodification with a defined amount of a nonfunctional phosphonic acid (variation of the functional/nonfunctional acid ratio). It was shown that the chain length and anchoring group size have significant effects on the alkyl chain ordering and morphology of the layer
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Diphosphonates
|2 NLM
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|a Organophosphonates
|2 NLM
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|a Phosphoric Acids
|2 NLM
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|a Phosphorus
|2 NLM
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|a 27YLU75U4W
|2 NLM
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|a Zirconium
|2 NLM
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|a C6V6S92N3C
|2 NLM
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|a phosphoric acid
|2 NLM
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|a E4GA8884NN
|2 NLM
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|a zirconium oxide
|2 NLM
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|a S38N85C5G0
|2 NLM
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1 |
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|a Feichtenschlager, Bernhard
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Moszner, Norbert
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Puchberger, Michael
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Müller, Klaus
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Abele, Matthias
|e verfasserin
|4 aut
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1 |
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|a Kickelbick, Guido
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 7 vom: 05. Apr., Seite 3534-40
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:27
|g year:2011
|g number:7
|g day:05
|g month:04
|g pages:3534-40
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|u http://dx.doi.org/10.1021/la104527b
|3 Volltext
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|d 27
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|e 7
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|h 3534-40
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