Effect of Microstructure on the Radioluminescence and Transparency of Ce-Doped Strontium Hafnate Ceramics

In this paper we report on the fabrication and characterization of SrHfO(3):Ce ceramics. Powders were prepared by solid-state synthesis using metal oxides and carbonates. X-ray diffraction measurements showed that phase-pure SrHfO(3) is formed at 1200°C. Inductively coupled plasma spectroscopy confi...

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Veröffentlicht in:Optical Materials. - 1998. - 33(2010), 1 vom: 01. Nov., Seite 84-90
1. Verfasser: van Loef, Edgar V (VerfasserIn)
Weitere Verfasser: Wang, Yimin, Miller, Stuart R, Brecher, Charles, Rhodes, William H, Baldoni, Gary, Topping, Stephen, Lingertat, Helmut, Sarin, Vinod K, Shah, Kanai S
Format: Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Optical Materials
Schlagworte:Journal Article
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245 1 0 |a Effect of Microstructure on the Radioluminescence and Transparency of Ce-Doped Strontium Hafnate Ceramics 
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520 |a In this paper we report on the fabrication and characterization of SrHfO(3):Ce ceramics. Powders were prepared by solid-state synthesis using metal oxides and carbonates. X-ray diffraction measurements showed that phase-pure SrHfO(3) is formed at 1200°C. Inductively coupled plasma spectroscopy confirmed the purity and composition of each batch. SrHfO(3) exhibits several phase changes in the solid, but this does not appear to be detrimental to the ceramics. Microprobe experiments showed uniform elemental grain composition, whereas aluminum added as charge compensation for trivalent cerium congregated at grain boundaries and triple points. Radioluminescence spectra revealed that the light yield decreases when the concentration of excess Sr increases. The decrease in the light yield may be related to the change of Ce(3+) into Ce(4+) ions. For stoichiometric SrHfO(3):Ce, the light yield is about four times that of bismuth germanate (BGO), the conventional benchmark, indicating great potential for many scintillator applications 
650 4 |a Journal Article 
700 1 |a Wang, Yimin  |e verfasserin  |4 aut 
700 1 |a Miller, Stuart R  |e verfasserin  |4 aut 
700 1 |a Brecher, Charles  |e verfasserin  |4 aut 
700 1 |a Rhodes, William H  |e verfasserin  |4 aut 
700 1 |a Baldoni, Gary  |e verfasserin  |4 aut 
700 1 |a Topping, Stephen  |e verfasserin  |4 aut 
700 1 |a Lingertat, Helmut  |e verfasserin  |4 aut 
700 1 |a Sarin, Vinod K  |e verfasserin  |4 aut 
700 1 |a Shah, Kanai S  |e verfasserin  |4 aut 
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