Tuning nanoscale friction on Pt nanoparticles with engineering of organic capping layer

Nanoscale friction and adhesion on Pt colloid nanoparticles coated with different organic capping layers were probed with atomic/friction force microscopy. Platinum colloid nanoparticles with four types of capping layers have been synthesized and used as model lubricant systems: TTAB (tetradecyltrim...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 6 vom: 15. März, Seite 2509-13
1. Verfasser: Park, Jeong Young (VerfasserIn)
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Nanoscale friction and adhesion on Pt colloid nanoparticles coated with different organic capping layers were probed with atomic/friction force microscopy. Platinum colloid nanoparticles with four types of capping layers have been synthesized and used as model lubricant systems: TTAB (tetradecyltrimethylammonium bromide), HDA (hexadecylamine), HDT (hexadecylthiol), and PVP (poly(vinylpyrrolidone)). Two-dimensional arrays of colloid nanoparticles were prepared using the Langmuir-Blodgett method. We found that the friction and adhesion properties on colloid nanoparticles are lower than those on a silicon surface. The variation of friction when changing the capping layers is ∼30%, and it appears that the friction depends on the packing and ordering of the capping layers. Partial removal of the capping layers using ultraviolet light (UV)-ozone surface treatment resulted in increased friction. These results suggest a new method of tuning nanometer scale friction and adhesion by engineering organic capping layers on nanoparticles 
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