Superhydrophobic and superoleophobic nanocellulose aerogel membranes as bioinspired cargo carriers on water and oil

We demonstrate that superhydrophobic and superoleophobic nanocellulose aerogels, consisting of fibrillar networks and aggregates with structures at different length scales, support considerable load on a water surface and also on oils as inspired by floatation of insects on water due to their superh...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 5 vom: 01. März, Seite 1930-4
1. Verfasser: Jin, Hua (VerfasserIn)
Weitere Verfasser: Kettunen, Marjo, Laiho, Ari, Pynnönen, Hanna, Paltakari, Jouni, Marmur, Abraham, Ikkala, Olli, Ras, Robin H A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Adhesives Gases Gels Membranes, Artificial Oils Silanes Water 059QF0KO0R mehr... Cellulose 9004-34-6
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245 1 0 |a Superhydrophobic and superoleophobic nanocellulose aerogel membranes as bioinspired cargo carriers on water and oil 
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500 |a Citation Status MEDLINE 
520 |a We demonstrate that superhydrophobic and superoleophobic nanocellulose aerogels, consisting of fibrillar networks and aggregates with structures at different length scales, support considerable load on a water surface and also on oils as inspired by floatation of insects on water due to their superhydrophobic legs. The aerogel is capable of supporting a weight nearly 3 orders of magnitude larger than the weight of the aerogel itself. The load support is achieved by surface tension acting at different length scales: at the macroscopic scale along the perimeter of the carrier, and at the microscopic scale along the cellulose nanofibers by preventing soaking of the aerogel thus ensuring buoyancy. Furthermore, we demonstrate high-adhesive pinning of water and oil droplets, gas permeability, light reflection at the plastron in water and oil, and viscous drag reduction of the fluorinated aerogel in contact with oil. We foresee applications including buoyant, gas permeable, dirt-repellent coatings for miniature sensors and other devices floating on generic liquid surfaces 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Gases  |2 NLM 
650 7 |a Gels  |2 NLM 
650 7 |a Membranes, Artificial  |2 NLM 
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650 7 |a 059QF0KO0R  |2 NLM 
650 7 |a Cellulose  |2 NLM 
650 7 |a 9004-34-6  |2 NLM 
700 1 |a Kettunen, Marjo  |e verfasserin  |4 aut 
700 1 |a Laiho, Ari  |e verfasserin  |4 aut 
700 1 |a Pynnönen, Hanna  |e verfasserin  |4 aut 
700 1 |a Paltakari, Jouni  |e verfasserin  |4 aut 
700 1 |a Marmur, Abraham  |e verfasserin  |4 aut 
700 1 |a Ikkala, Olli  |e verfasserin  |4 aut 
700 1 |a Ras, Robin H A  |e verfasserin  |4 aut 
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773 1 8 |g volume:27  |g year:2011  |g number:5  |g day:01  |g month:03  |g pages:1930-4 
856 4 0 |u http://dx.doi.org/10.1021/la103877r  |3 Volltext 
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