Giant brainlike aggregates from new fluorocarbon/hydrocarbon hybrid cationic surfactants

A rapid synthetic procedure in two steps from perfluoroalkylethyl iodide derivatives led to 18 novel ammonium type hybrid surfactants of the general formula: R(F)(CH(2))(2)S(CH(2))(2)N(+)(CH(3))(2)R(H)Br(-) (R(F) = C(4)F(9), C(6)F(13), C(8)F(17); R(H) = C(4)H(9), C(6)H(13), C(8)H(17), C(10)H(21), C(...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 5 vom: 01. März, Seite 1668-74
1. Verfasser: Oumar, Mamadou (VerfasserIn)
Weitere Verfasser: Taffin de Givenchy, Elisabeth, Dieng, Samba Yandé, Amigoni, Sonia, Guittard, Frédéric
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Fluorocarbons Micelles Solutions Surface-Active Agents
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520 |a A rapid synthetic procedure in two steps from perfluoroalkylethyl iodide derivatives led to 18 novel ammonium type hybrid surfactants of the general formula: R(F)(CH(2))(2)S(CH(2))(2)N(+)(CH(3))(2)R(H)Br(-) (R(F) = C(4)F(9), C(6)F(13), C(8)F(17); R(H) = C(4)H(9), C(6)H(13), C(8)H(17), C(10)H(21), C(12)H(25), C(14)H(29)). These hybrid surfactants exhibited very low surface tension (from 16 to 25 mN/m) as well as low critical micellar concentration until 1.5 × 10(-5) mol/L. A special focus was made on aggregation phenomenon as giant multilamellar "brainlike" vesicles were observed via cryogenic scanning electron microscopy (cryoSEM) and transmission electron microscopy (TEM; with a contrast agent) suggesting a high encapsulation ability and a very important specific surface of these particular organizations 
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700 1 |a Taffin de Givenchy, Elisabeth  |e verfasserin  |4 aut 
700 1 |a Dieng, Samba Yandé  |e verfasserin  |4 aut 
700 1 |a Amigoni, Sonia  |e verfasserin  |4 aut 
700 1 |a Guittard, Frédéric  |e verfasserin  |4 aut 
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