Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes Synthesis, Solid-State Structures, and Quantum Chemistry Calculations

Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes : Synthesis, Solid-State Structures, and Quantum Chemistry Calculations

The reaction of (η(5)-C(5)H(5))Co(PPh(3))(2) with 1,3-bis(isopropyl)imidazol-2-ylidene (Im(i)Pr(2)) leads to the formation of (η(5)-C(5)H(5))Co(PPh(3))(Im(i)Pr(2)). In a similar fashion (η(5)-C(5)H(5))Co(Im(i)Pr(2))(CO) is formed from (η(5)-C(5)H(5))Co(CO)(2). The barrier to rotation about the Co-C(...

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Détails bibliographiques
Publié dans:Organometallics. - 1998. - 29(2010), 24 vom: 27. Dez., Seite 6695-6702
Auteur principal: Vélez, Carmen L (Auteur)
Autres auteurs: Markwick, Phineus R L, Holland, Ryan L, Dipasquale, Antonio G, Rheingold, Arnold L, O'Connor, Joseph M
Format: Article
Langue:English
Publié: 2010
Accès à la collection:Organometallics
Sujets:Journal Article