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231223s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la104586t
|2 doi
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|a pubmed24n0682.xml
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|a (NLM)21189004
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|a DE-627
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|e rakwb
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|a eng
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1 |
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|a Ji, Eunkyung
|e verfasserin
|4 aut
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|a pH-dependent optical properties of a poly(phenylene ethynylene) conjugated polyampholyte
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|c 2011
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|a Text
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|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 07.06.2011
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|a Date Revised 25.11.2016
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a A poly(phenylene ethynylene) conjugated polymer (PPE-NMe(3)(+)-COO(-)) containing tetraalkylammonium groups and carboxylate groups has been synthesized by Sonogashira coupling. Due to the presence of the strong cationic and weak anionic pendant units, the polymer undergoes a pH-induced transition from cationic polyelectrolyte to polyampholyte due to deprotonation of the carboxylic acid units in basic solution. Studies of the pH dependence of the polymers' optical properties reveal changes in absorption oscillator strength and fluorescence quantum efficiency that are triggered by the transition from cationic polyelectrolyte to polyampholyte nature. Stern-Volmer fluorescence quenching of PPE-NMe(3)(+)-COO(-) with a negatively charged quencher 1,4,5,8-naphthalenediimide-N,N-bis(methylsulfonate) (NDS) shows that the polymer fluorescence quenching is amplified at low pH where the polymer is a polycation, whereas the quenching efficiency is considerably less at high pH
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|a Journal Article
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a Carboxylic Acids
|2 NLM
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|a Polymers
|2 NLM
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|a Quaternary Ammonium Compounds
|2 NLM
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|a Solutions
|2 NLM
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|a poly(phenylene ethynylene)
|2 NLM
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|a Whitten, David G
|e verfasserin
|4 aut
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|a Schanze, Kirk S
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 5 vom: 01. März, Seite 1565-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:27
|g year:2011
|g number:5
|g day:01
|g month:03
|g pages:1565-8
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|u http://dx.doi.org/10.1021/la104586t
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