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231223s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la103641w
|2 doi
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|a pubmed24n0682.xml
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|a eng
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|a Clair, Sylvain
|e verfasserin
|4 aut
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|a Coverage-dependent formation of chiral ethylthiolate-Au complexes on Au(111)
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 05.05.2011
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|a Date Revised 11.01.2011
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a We studied the coverage-dependent self-assembly of the flat-lying phase of ethylthiolate on Au(111). At low coverage, we observed the formation of short stripes of chiral Au-(SC(2)H(5))(2) complexes that arrange in a disordered phase. The latter grow partly at the expense of the native Au(111) surface reconstruction, which is fully lifted for a coverage of ∼0.60 ML. We found that the lift of the reconstruction and evaporation from step edges are competing adatom sources. Close to saturation coverage (0.70 to 0.75 ML), large, well-ordered domains with a (8 × √3)rectangular superstructure formed. Alternation of chirality was found in adjacent stripes as already reported for other short alkanethiolates. We suggest that, because of a simple geometrical consideration, the chirality should, on the contrary, be preserved in the stripe phase of longer alkanethiolates
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Organometallic Compounds
|2 NLM
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|a Sulfhydryl Compounds
|2 NLM
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|a Gold
|2 NLM
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|a 7440-57-5
|2 NLM
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|a Kim, Yousoo
|e verfasserin
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|a Kawai, Maki
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 2 vom: 18. Jan., Seite 627-9
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|g volume:27
|g year:2011
|g number:2
|g day:18
|g month:01
|g pages:627-9
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|u http://dx.doi.org/10.1021/la103641w
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