Precise adsorption behavior and mechanism of Ni(II) ions on nano-hydroxyapatite

The goal of this study was to synthesize use of hydroxyapatite as a high-efficiency adsorbent for Ni(II) ions, and to study its adsorption behavior. Three tests--Fourier-transform infrared spectroscopy, transmission electron microscopy, and Brunauer-Emmett-Teller were carried out to determine the ch...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 82(2010), 11 vom: 15. Nov., Seite 2279-84
1. Verfasser: Zhang, Jun (VerfasserIn)
Weitere Verfasser: Wang, Deping, Zhou, Jun, Yao, Aihua, Huang, Wenhai
Format: Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Nickel 7OV03QG267 Durapatite 91D9GV0Z28
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520 |a The goal of this study was to synthesize use of hydroxyapatite as a high-efficiency adsorbent for Ni(II) ions, and to study its adsorption behavior. Three tests--Fourier-transform infrared spectroscopy, transmission electron microscopy, and Brunauer-Emmett-Teller were carried out to determine the chemical functionality of the hydroxyapatite powders, to observe its crystal morphology, and to measure the specific surface area. Results indicate that proves the n-HA synthesized by chemical precipitation is an effective adsorbent for the removal of Ni(II) ions from water solution. The synthesized, needle-like nano-hydroxyapatite (n-HA) have a uniform average size of 31.9 X 21.3nm, a large specific surface area (135 m2/g), and typically is a weak crystal with a broad pore distribution. The adsorption isotherm shows the Langmuir model is applicable only when the initial Ni2+ concentration is lower than 0.1 mol/L. Multilayer adsorption was attributed to uneven pore distribution that occurred at higher Ni2+ concentration. The adsorption of Ni2+ onto n-HA was attributed to electrostatic attraction, ion exchange, and dissolution-precipitation reaction. As the result, Ni2+ substitutes Ca2+ and binds with the oxygen atom on the surface, which resulted from the change in crystal-phase composition and in the binding energy of surface elements of n-HA before and after adsorption 
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700 1 |a Wang, Deping  |e verfasserin  |4 aut 
700 1 |a Zhou, Jun  |e verfasserin  |4 aut 
700 1 |a Yao, Aihua  |e verfasserin  |4 aut 
700 1 |a Huang, Wenhai  |e verfasserin  |4 aut 
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