Preparation of hybrid film of polyaniline and organically pillared zirconium phosphate nanosheet by electrodeposition

α-Zirconium phosphate was chemically modified with 1,2-bis(dimethylchlorosilyl)ethane to graft organic chain, and then it was used as host material for inorganic nanosheet-polyaniline hybrid. The grafted α-zirconium phosphate was exfoliated in an acetonitrile solution with tetrabutylammonium salt an...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 27(2011), 1 vom: 04. Jan., Seite 126-31
1. Verfasser: Takei, Takahiro (VerfasserIn)
Weitere Verfasser: Dong, Qiang, Yonesaki, Yoshinori, Kumada, Nobuhiro, Kinomura, Nobukazu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2011
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Preparation of hybrid film of polyaniline and organically pillared zirconium phosphate nanosheet by electrodeposition 
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520 |a α-Zirconium phosphate was chemically modified with 1,2-bis(dimethylchlorosilyl)ethane to graft organic chain, and then it was used as host material for inorganic nanosheet-polyaniline hybrid. The grafted α-zirconium phosphate was exfoliated in an acetonitrile solution with tetrabutylammonium salt and aniline. The electrodeposition in the presence of aniline was performed, and then it resulted in a formation of higher-order structure in which phosphate nanosheet was propped up by 1,2-bis(dimethylchlorosilyl)ethane with intrusion of polyaniline into the nanospace. The gravimetric capacitance of the α-zirconium phosphate without grafts and polyaniline hybrid film was around 194 F/g with the base on the amount of polyaniline mass. On the other hand, the α-zirconium phosphate nanosheet with grafts and polyaniline hybrid film provided larger capacitance of around 350 F/g in maximum. The nanospace formed by grafted phosphate nanosheet with 1,2-bis(dimethylchlorosilyl)ethane molecules gives increased amounts of polyaniline included and diffusion paths for ions 
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700 1 |a Dong, Qiang  |e verfasserin  |4 aut 
700 1 |a Yonesaki, Yoshinori  |e verfasserin  |4 aut 
700 1 |a Kumada, Nobuhiro  |e verfasserin  |4 aut 
700 1 |a Kinomura, Nobukazu  |e verfasserin  |4 aut 
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