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231223s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la102198j
|2 doi
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|a pubmed24n0680.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Takei, Takahiro
|e verfasserin
|4 aut
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|a Preparation of hybrid film of polyaniline and organically pillared zirconium phosphate nanosheet by electrodeposition
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|c 2011
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 12.04.2011
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|a Date Revised 28.12.2010
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a α-Zirconium phosphate was chemically modified with 1,2-bis(dimethylchlorosilyl)ethane to graft organic chain, and then it was used as host material for inorganic nanosheet-polyaniline hybrid. The grafted α-zirconium phosphate was exfoliated in an acetonitrile solution with tetrabutylammonium salt and aniline. The electrodeposition in the presence of aniline was performed, and then it resulted in a formation of higher-order structure in which phosphate nanosheet was propped up by 1,2-bis(dimethylchlorosilyl)ethane with intrusion of polyaniline into the nanospace. The gravimetric capacitance of the α-zirconium phosphate without grafts and polyaniline hybrid film was around 194 F/g with the base on the amount of polyaniline mass. On the other hand, the α-zirconium phosphate nanosheet with grafts and polyaniline hybrid film provided larger capacitance of around 350 F/g in maximum. The nanospace formed by grafted phosphate nanosheet with 1,2-bis(dimethylchlorosilyl)ethane molecules gives increased amounts of polyaniline included and diffusion paths for ions
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|a Journal Article
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|a Dong, Qiang
|e verfasserin
|4 aut
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|a Yonesaki, Yoshinori
|e verfasserin
|4 aut
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|a Kumada, Nobuhiro
|e verfasserin
|4 aut
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|a Kinomura, Nobukazu
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 1 vom: 04. Jan., Seite 126-31
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:27
|g year:2011
|g number:1
|g day:04
|g month:01
|g pages:126-31
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|u http://dx.doi.org/10.1021/la102198j
|3 Volltext
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