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231223s2011 xx |||||o 00| ||eng c |
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|a 10.1021/la103936t
|2 doi
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|a pubmed24n0680.xml
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Motiei, Leila
|e verfasserin
|4 aut
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|a Synergism in multicomponent self-propagating molecular assemblies
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|c 2011
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|a Text
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 26.05.2011
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|a Date Revised 09.02.2011
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Multicomponent self-propagating molecular assemblies (SPMAs) have been generated from an organic chromophore, a redox-active polypyridyl complex, and PdCl(2). The structure of the multicomponent SPMA is not a linear combination of two assemblies generated with a single molecular constituent. Surface-confined assemblies formed from only the organic chromophore and PdCl(2) are known to follow linear growth, whereas the combination of polypyridyl complexes and PdCl(2) results in exponential growth. The present study demonstrates that an iterative deposition of both molecular building blocks with PdCl(2) results in an exponentially growing assembly. The nature of the assembly mechanism is dictated by the polypyridyl complex and overrides the linear growth process of the organic component. Relatively smooth, multicomponent SPMAs have been obtained with a thickness of ∼20 nm on silicon, glass, and indium-tin oxide (ITO) coated glass. Detailed information of the structure and of the surface-assembly chemistry were obtained using transmission optical (UV/Vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), synchrotron X-ray reflectivity (XRR), and electrochemistry
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|a Journal Article
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1 |
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|a Sassi, Mauro
|e verfasserin
|4 aut
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1 |
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|a Kaminker, Revital
|e verfasserin
|4 aut
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|a Evmenenko, Guennadi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Dutta, Pulak
|e verfasserin
|4 aut
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|a Iron, Mark A
|e verfasserin
|4 aut
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|a van der Boom, Milko E
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 27(2011), 4 vom: 15. Feb., Seite 1319-25
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:27
|g year:2011
|g number:4
|g day:15
|g month:02
|g pages:1319-25
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|u http://dx.doi.org/10.1021/la103936t
|3 Volltext
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