Space-filling trialkoxysilane : synthesis and self-assembly into low-density monolayers

A novel space-filling trialkoxysilane derivative was synthesized using a two-step strategy from commercially available starting materials to produce the precursor for the formation of low-density self-assembled monolayers. Self-assembled monolayers of the synthesized compound were prepared on three...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 26(2010), 24 vom: 21. Dez., Seite 18628-30
1. Verfasser: Subramanian, Nithya (VerfasserIn)
Weitere Verfasser: Schmidt, Rolf, Wood-Adams, Paula M, DeWolf, Christine E
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a A novel space-filling trialkoxysilane derivative was synthesized using a two-step strategy from commercially available starting materials to produce the precursor for the formation of low-density self-assembled monolayers. Self-assembled monolayers of the synthesized compound were prepared on three different substrates (Si/SiO(2), glass and ITO) and were characterized using contact angle, ellipsometry and sum-frequency generation spectroscopy. Removal of the space-filling protecting group, (2-chlorophenyl)diphenyl methanol, yields a carboxy-terminated surface. Correspondingly, the contact angle and film thickness decrease and the SFG spectra clearly indicate an increase in gauche defect concentration characteristic of a low-density disordered monolayer 
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700 1 |a Wood-Adams, Paula M  |e verfasserin  |4 aut 
700 1 |a DeWolf, Christine E  |e verfasserin  |4 aut 
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