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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la104059p
|2 doi
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|a (NLM)21090761
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|a DE-627
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|e rakwb
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|a eng
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|a Subramanian, Nithya
|e verfasserin
|4 aut
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|a Space-filling trialkoxysilane
|b synthesis and self-assembly into low-density monolayers
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 17.03.2011
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|a Date Revised 14.12.2010
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a A novel space-filling trialkoxysilane derivative was synthesized using a two-step strategy from commercially available starting materials to produce the precursor for the formation of low-density self-assembled monolayers. Self-assembled monolayers of the synthesized compound were prepared on three different substrates (Si/SiO(2), glass and ITO) and were characterized using contact angle, ellipsometry and sum-frequency generation spectroscopy. Removal of the space-filling protecting group, (2-chlorophenyl)diphenyl methanol, yields a carboxy-terminated surface. Correspondingly, the contact angle and film thickness decrease and the SFG spectra clearly indicate an increase in gauche defect concentration characteristic of a low-density disordered monolayer
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|a Journal Article
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|a Schmidt, Rolf
|e verfasserin
|4 aut
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|a Wood-Adams, Paula M
|e verfasserin
|4 aut
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|a DeWolf, Christine E
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 26(2010), 24 vom: 21. Dez., Seite 18628-30
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:26
|g year:2010
|g number:24
|g day:21
|g month:12
|g pages:18628-30
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|u http://dx.doi.org/10.1021/la104059p
|3 Volltext
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|d 26
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