Transfer of biosynthesized gold nanoparticles from water into an ionic liquid using alkyltrimethyl ammonium bromide : an anion-exchange process

Biosynthesized gold nanoparticles (GNPs) were transferred from water to a hydrophobic ionic liquid (IL), [Bmim]PF(6), with the assistance of alkyl trimethyl ammonium bromide. The phase transfer mechanism was illustrated through the exemplification of cetyltrimethyl ammonium bromide (CTAB). Interacti...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:	Langmuir : the ACS journal of surfaces and colloids. - 1985. - 27(2011), 1 vom: 04. Jan., Seite 166-9
1. Verfasser:	Zhou, Yao (VerfasserIn)
Weitere Verfasser:	Lin, Wenshuang, Wang, Huixuan, Li, Qingbiao, Huang, Jiale, Du, Mingming, Lin, Liqin, Gao, Yixian, Lin, Ling, He, Ning
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2011
Zugriff auf das übergeordnete Werk:	Langmuir : the ACS journal of surfaces and colloids
Schlagworte:	Journal Article Research Support, Non-U.S. Gov't 1-butyl-3-methylimidazolium hexafluorophosphate Cetrimonium Compounds Imidazoles Ionic Liquids Water 059QF0KO0R Gold 7440-57-5 mehr... Cetrimonium Z7FF1XKL7A

Beschreibung
Zusammenfassung:	Biosynthesized gold nanoparticles (GNPs) were transferred from water to a hydrophobic ionic liquid (IL), [Bmim]PF(6), with the assistance of alkyl trimethyl ammonium bromide. The phase transfer mechanism was illustrated through the exemplification of cetyltrimethyl ammonium bromide (CTAB). Interaction between GNPs and CTAB was demonstrated through zeta potential analysis. Moreover, an anion-exchange process was discovered between CTAB and IL. During the process, the hydrophobic CTAPF(6) formed in situ on the GNPs led to the hydrophobization and thus phase transfer of the GNPs. The phase transfer efficiency was found to be size-dependent
Beschreibung:	Date Completed 12.04.2011 Date Revised 01.12.2018 published: Print-Electronic Citation Status MEDLINE
ISSN:	1520-5827
DOI:	10.1021/la103586f