Effects of potassium on the supramolecular structure and electronic properties of eumelanin thin films

The role of potassium in the formation of synthetic eumelanin aggregates is investigated by atomic force microscopy and soft-X-ray spectroscopy. Control over the thin film granularity is achieved by using K salts, in both drop casting and electrodeposition of eumelanin thin films. Further control ov...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 24 vom: 21. Dez., Seite 19007-13
1. Verfasser: Borghetti, Patrizia (VerfasserIn)
Weitere Verfasser: Goldoni, Andrea, Castellarin-Cudia, Carla, Casalis, Loredana, Herberg, Fabian, Floreano, Luca, Cossaro, Albano, Verdini, Alberto, Gebauer, Ralph, Ghosh, Prasenjit, Sangaletti, Luigi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Aluminum Silicates Bromides Melanins Potassium Compounds Tin Compounds eumelanin 12627-86-0 indium tin oxide 71243-84-0 mehr... Gold 7440-57-5 potassium bromide OSD78555ZM Potassium RWP5GA015D mica V8A1AW0880 Dimethyl Sulfoxide YOW8V9698H
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520 |a The role of potassium in the formation of synthetic eumelanin aggregates is investigated by atomic force microscopy and soft-X-ray spectroscopy. Control over the thin film granularity is achieved by using K salts, in both drop casting and electrodeposition of eumelanin thin films. Further control over orientation is made possible by a suitable choice of the substrate: evidence of self-assembly is found for thin films deposited on gold. Finally, it is shown that the potassium content affects not only the samples morphology, but also the low-lying states in the valence band, where a transfer of spectral weight across the HOMO-LUMO gap is observed, disclosing possible applications of this multifunctional biomacromolecule 
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650 7 |a Bromides  |2 NLM 
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650 7 |a mica  |2 NLM 
650 7 |a V8A1AW0880  |2 NLM 
650 7 |a Dimethyl Sulfoxide  |2 NLM 
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700 1 |a Goldoni, Andrea  |e verfasserin  |4 aut 
700 1 |a Castellarin-Cudia, Carla  |e verfasserin  |4 aut 
700 1 |a Casalis, Loredana  |e verfasserin  |4 aut 
700 1 |a Herberg, Fabian  |e verfasserin  |4 aut 
700 1 |a Floreano, Luca  |e verfasserin  |4 aut 
700 1 |a Cossaro, Albano  |e verfasserin  |4 aut 
700 1 |a Verdini, Alberto  |e verfasserin  |4 aut 
700 1 |a Gebauer, Ralph  |e verfasserin  |4 aut 
700 1 |a Ghosh, Prasenjit  |e verfasserin  |4 aut 
700 1 |a Sangaletti, Luigi  |e verfasserin  |4 aut 
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