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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la102074a
|2 doi
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|a pubmed24n0675.xml
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|a eng
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|a Cheong, Wai Yeng
|e verfasserin
|4 aut
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| 245 |
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|a Probing enantioselectivity on chirally modified Cu(110), Cu(100), and Cu(111) surfaces
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 07.02.2011
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|a Date Revised 21.11.2013
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|a published: Print
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|a Citation Status MEDLINE
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|a Temperature programmed desorption methods have been used to probe the enantioselectivity of achiral Cu(100), Cu(110), and Cu(111) single crystal surfaces modified by chiral organic molecules including amino acids, alcohols, alkoxides, and amino-alcohols. The following combinations of chiral probes and chiral modifiers on Cu surfaces were included in this study: propylene oxide (PO) on L-alanine modified Cu(110), PO on L-alaninol modified Cu(111), PO on 2-butanol modified Cu(111), PO on 2-butoxide modified Cu(100), PO on 2-butoxide modified Cu(111), R-3-methylcyclohexanone (R-3-MCHO) on 2-butoxide modified Cu(100), and R-3-MCHO on 2-butoxide modified Cu(111). In contrast with the fact that these and other chiral probe/modifier systems have exhibited enantioselectivity on Pd(111) and Pt(111) surfaces, none of these probe/modifier/Cu systems exhibit enantioselectivity at either low or high modifier coverages. The nature of the underlying substrate plays a significant role in the mechanism of hydrogen-bonding interactions and could be critical to observing enantioselectivity. While hydrogen-bonding interactions between modifier and probe molecule are believed to induce enantioselectivity on Pd surfaces (Gao, F.; Wang, Y.; Burkholder, L.; Tysoe, W. T. J. Am. Chem. Soc. 2007, 129, 15240-15249), such critical interactions may be missing on Cu surfaces where hydrogen-bonding interactions are believed to occur between adjacent modifier molecules, enabling them to form clusters or islands
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|a Journal Article
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|a Research Support, U.S. Gov't, Non-P.H.S.
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|a Alcohols
|2 NLM
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|a Amino Acids
|2 NLM
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|a Oxides
|2 NLM
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|a Copper
|2 NLM
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| 650 |
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|a 789U1901C5
|2 NLM
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| 700 |
1 |
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|a Huang, Ye
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Dangaria, Nikunj
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Gellman, Andrew J
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 26(2010), 21 vom: 02. Nov., Seite 16412-23
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:26
|g year:2010
|g number:21
|g day:02
|g month:11
|g pages:16412-23
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|u http://dx.doi.org/10.1021/la102074a
|3 Volltext
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