Perfluorophenyl azide immobilization chemistry for single molecule force spectroscopy of the concanavalin A/mannose interaction

The versatility of perfluorophenyl azide (PFPA) derivatives makes them useful for attaching a wide variety of biomolecules and polymers to surfaces. Herein, a single molecule force spectroscopy (SMFS) study of the concanavalin A/mannose interaction was carried out using PFPA immobilization chemistry...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 26(2010), 22 vom: 16. Nov., Seite 16677-80
1. Verfasser: Madwar, Carolin (VerfasserIn)
Weitere Verfasser: Kwan, William Chu, Deng, Lingquan, Ramström, Olof, Schmidt, Rolf, Zou, Shan, Cuccia, Louis A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Azides Hydrocarbons, Fluorinated perfluorophenyl azide Concanavalin A 11028-71-0 Mannose PHA4727WTP
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520 |a The versatility of perfluorophenyl azide (PFPA) derivatives makes them useful for attaching a wide variety of biomolecules and polymers to surfaces. Herein, a single molecule force spectroscopy (SMFS) study of the concanavalin A/mannose interaction was carried out using PFPA immobilization chemistry. SMFS of the concanavalin A/mannose interaction yielded an average unbinding force of 70-80 pN for loading rates between 8000 and 40,000 pN/s for mannose surfaces on aminated glass, and an unbinding force of 57 ± 20 pN at 6960 pN/s for mannose surfaces on gold-coated glass. Dynamic force spectroscopy was used to determine the dissociation rate constant, k(off), for this interaction to be 0.16 s(-1) 
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650 4 |a Research Support, Non-U.S. Gov't 
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650 7 |a Hydrocarbons, Fluorinated  |2 NLM 
650 7 |a perfluorophenyl azide  |2 NLM 
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700 1 |a Kwan, William Chu  |e verfasserin  |4 aut 
700 1 |a Deng, Lingquan  |e verfasserin  |4 aut 
700 1 |a Ramström, Olof  |e verfasserin  |4 aut 
700 1 |a Schmidt, Rolf  |e verfasserin  |4 aut 
700 1 |a Zou, Shan  |e verfasserin  |4 aut 
700 1 |a Cuccia, Louis A  |e verfasserin  |4 aut 
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