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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la1032477
|2 doi
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|a pubmed24n0674.xml
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|a (DE-627)NLM202306941
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|a (NLM)20939496
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Nagatani, Hirohisa
|e verfasserin
|4 aut
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|a Encapsulation of anilinonaphthalenesulfonates in carboxylate-terminated PAMAM dendrimer at the polarized water|1,2-dichloroethane interface
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 04.03.2011
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|a Date Revised 21.11.2013
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Molecular encapsulation of water-soluble anionic fluorescent dye molecules, 8-anilino-1-naphthalenesulfonic acid (ANS), and its bimolecular derivative (bis-ANS), in the generation 3.5 polyamidoamine (G3.5 PAMAM) dendrimer was investigated in the bulk aqueous phase and at the polarized water|1,2-dichloroethane interface. ANS(-) was electrostatically incorporated in the dendrimer, and the fluorescence enhancement with a blue shift of the emission maximum was observed at pH values <6, where the interior of the dendrimer was positively charged. The fluorescence enhancement of ANS was maximized around pH 3 and then decreased under more acidic conditions. The potential dependences of the molecular encapsulation and the interfacial mechanism were studied in detail by means of potential modulated fluorescence (PMF) spectroscopy. Under acidic conditions, the dendrimer incorporated ANS(-) at the positively polarized interface as well as in the aqueous phase. ANS(-) was released from the dendrimer at the intrinsic transfer potential and independently transferred across the interface. Bis-ANS exhibited relatively strong interaction with the dendrimer over a wide pH range (1 < pH < 8), and a negative shift of the transfer potential was observed under the corresponding pH condition. The PMF analysis clearly demonstrated that the interfacial mechanism of the dendrimer involves transfer and adsorption processes depending on the pH condition and the Galvani potential difference
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a 8-anilino-1-naphthalenesulfonic acid
|2 NLM
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|a Anilino Naphthalenesulfonates
|2 NLM
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|a Carboxylic Acids
|2 NLM
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|a Dendrimers
|2 NLM
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|a Ethylene Dichlorides
|2 NLM
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|a Fluorescent Dyes
|2 NLM
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|a Naphthalenesulfonates
|2 NLM
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|a PAMAM Starburst
|2 NLM
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|a Water
|2 NLM
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|a 059QF0KO0R
|2 NLM
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|a ethylene dichloride
|2 NLM
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|a 55163IJI47
|2 NLM
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1 |
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|a Sakamoto, Tsutomu
|e verfasserin
|4 aut
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1 |
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|a Torikai, Taishi
|e verfasserin
|4 aut
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|a Sagara, Takamasa
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 26(2010), 22 vom: 16. Nov., Seite 17686-94
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:26
|g year:2010
|g number:22
|g day:16
|g month:11
|g pages:17686-94
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|u http://dx.doi.org/10.1021/la1032477
|3 Volltext
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