The CO formation reaction pathway in steam methane reforming by rhodium

Three different pathways toward CO formation from adsorbed CH and O are compared by quantum-chemical density functional theory (DFT) calculations for planar and stepped Rh surfaces. The conventional pathway competes with the pathway involving a formyl (CHO) species. This holds for both types of surf...

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Bibliographische Detailangaben

Veröffentlicht in:	Langmuir : the ACS journal of surfaces and colloids. - 1985. - 26(2010), 21 vom: 02. Nov., Seite 16339-48
1. Verfasser:	van Grootel, Pieter W (VerfasserIn)
Weitere Verfasser:	Hensen, Emiel J M, van Santen, Rutger A
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2010
Zugriff auf das übergeordnete Werk:	Langmuir : the ACS journal of surfaces and colloids
Schlagworte:	Journal Article Research Support, Non-U.S. Gov't Gases Carbon Monoxide 7U1EE4V452 Rhodium DMK383DSAC Methane OP0UW79H66