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231223s2010 xx |||||o 00| ||eng c |
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|a 10.1021/la1029905
|2 doi
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|a eng
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|a Das, Rajat K
|e verfasserin
|4 aut
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|a Supramolecular chirality in organogels
|b a detailed spectroscopic, morphological, and rheological investigation of gels (and xerogels) derived from alkyl pyrenyl urethanes
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|c 2010
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 21.01.2011
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|a Date Revised 12.10.2010
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a This Article addresses the formation of chiral supramolecular structures in the organogels derived from chiral organogelator 1R (or 2R), and its mixtures with its enantiomer (1S) and achiral analogue 3 by extensive circular dichroism (CD) spectroscopic measurements. Morphological analysis by atomic force microscopy (AFM) and scanning electron microscopy (SEM) were complemented by the measurements of their bulk properties by thermal stability and rheological studies. Specific molecular recognition events (1/3 vs 2/3) and solvent effects (isooctane vs dodecane) were found to be critical in the formation of chiral aggregates. Theoretical studies were also carried out to understand the interactions responsible for the formation of the superstructures
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|a Journal Article
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|a Kandanelli, Ramesh
|e verfasserin
|4 aut
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|a Linnanto, Juha
|e verfasserin
|4 aut
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|a Bose, Kunal
|e verfasserin
|4 aut
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|a Maitra, Uday
|e verfasserin
|4 aut
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773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 26(2010), 20 vom: 19. Okt., Seite 16141-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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|g volume:26
|g year:2010
|g number:20
|g day:19
|g month:10
|g pages:16141-9
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|u http://dx.doi.org/10.1021/la1029905
|3 Volltext
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