Kinetic and theoretical study of the hydrodechlorination of CH(4-x)Cl(x) (x = 1-4) compounds on palladium

The reaction kinetics of hydrodechlorination (HDCl) for a series of CH(4−x)Cl(x) (x = 1−4) compounds were measured on a Pd/carbon catalyst. The rate of HDCl correlated with the C−Cl bond energy, suggesting scission of this bond in the molecularly adsorbed molecule is rate-determining. The measured r...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Langmuir : the ACS journal of surfaces and colloids. - 1999. - 26(2010), 21 vom: 02. Nov., Seite 16615-24
1. Verfasser:	Chen, Nan (VerfasserIn)
Weitere Verfasser:	Rioux, Robert M, Barbosa, Luis A M M, Ribeiro, Fabio H
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2010
Zugriff auf das übergeordnete Werk:	Langmuir : the ACS journal of surfaces and colloids
Schlagworte:	Journal Article Hydrocarbons, Chlorinated Palladium 5TWQ1V240M