Charge partitioning at gas-solid interfaces : humidity causes electricity buildup on metals

Isolated metals within Faraday cages spontaneously acquire charge at relative humidity above 50%: aluminum and chrome-plated brass become negative, stainless steel is rendered positive, and copper remains almost neutral. Isolated metal charging within shielded and grounded containers confirms that t...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 17 vom: 07. Sept., Seite 13763-6
1. Verfasser: Ducati, Telma R D (VerfasserIn)
Weitere Verfasser: Simões, Luís H, Galembeck, Fernando
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:Isolated metals within Faraday cages spontaneously acquire charge at relative humidity above 50%: aluminum and chrome-plated brass become negative, stainless steel is rendered positive, and copper remains almost neutral. Isolated metal charging within shielded and grounded containers confirms that the atmosphere is an electric charge reservoir where OH(-) and H(+) ions transfer to gas-solid interfaces, producing net current. The electricity buildup dependence on humidity, or hygroelectricity, acts simultaneously but in opposition to the well-known charge dissipation due to the increase in surface conductance of solids under high humidity. Acknowledging this dual role of humidity improves the reproducibility of electrostatic experiments
Beschreibung:Date Completed 27.12.2010
Date Revised 02.09.2010
published: Print
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/la102494k