Biomimetic synthesis of multilayered aragonite aggregates using alginate as crystal growth modifier
Polysaccharides were believed to play an important role in the mineralization process of many organisms. As the source of continuously and uniformly releasing alginate molecules and Ca(2+), alginate/Ca nanospherical gel was employed in the solution to induce the nucleation and growth of CaCO(3). Tim...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 26(2010), 16 vom: 17. Aug., Seite 13385-92 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2010
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't Alginates Hexuronic Acids Glucuronic Acid 8A5D83Q4RW Calcium Carbonate H0G9379FGK |
| Zusammenfassung: | Polysaccharides were believed to play an important role in the mineralization process of many organisms. As the source of continuously and uniformly releasing alginate molecules and Ca(2+), alginate/Ca nanospherical gel was employed in the solution to induce the nucleation and growth of CaCO(3). Time-resolved transmission electron microscopy (TEM) was applied to study the crystallization at a very early stage. It was found that the initially formed lens-like vaterite particles gradually dissolved from the middle of the particle and released alginate molecules and Ca(2+) back into the system. As reaction time increased, the released substances were involved in the next stage of crystallization of CaCO(3), in the form of needle-like and shuttle-like aragonite particles sequentially depending on the concentration of alginate molecules and Ca(2+). "Egg-box" conformation of alginate and Ca(2+) was considered a skeleton for the growth of such aragonite particles. Notably, shuttle-like aragonite particles were composed of "bricks" of several hundred nanometers in size, which were very similar to biogenetic nacreous layers in shells |
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| Beschreibung: | Date Completed 22.11.2010 Date Revised 01.12.2018 published: Print Citation Status MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la102191q |